I. K. Rubtsova, S. N. Melnikov, M. A. Shmelev, S. A. Nikolaevskii, I. A. Yakushev, J. K. Voronina, E. D. Barabanova, M. A. Kiskin, A. A. Sidorov, I. L. Eremenko, “Facile synthesis and structure elucidation of metal-organic frameworks with {ZnCa} and {Zn<sub>2</sub>Ca} metal cores”, Mendeleev Commun., 2020, Volume 30, Issue 6,Pages <nobr>722

This article is cited in 17 papers

Communications

Facile synthesis and structure elucidation of metal-organic frameworks with {ZnCa} and {Zn₂Ca} metal cores

I. K. Rubtsova^a, S. N. Melnikov^a, M. A. Shmelev^a, S. A. Nikolaevskii^a, I. A. Yakushev^a, J. K. Voronina^a, E. D. Barabanova^b, M. A. Kiskin^a, A. A. Sidorov^a, I. L. Eremenko^a

^a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Samara Center for Theoretical Materials Science (SCTMS), Samara National Research University, Samara, Russian Federation

Abstract: The [ZnCa(DMF)₂(tda)₂]_n·nDMF and [Zn₂Ca(fda)₄]_n·2n(Me₂NH₂) metal-organic frameworks have been obtained by the reactions of pre-synthesized [Zn₂Ca(piv)₆(py)₂] (piv is pivalate, and py is pyridine) with 2,5-thiophenedicarboxylic (H₂tda) and 2,5-furandicarboxylic (H₂fda) acids, respectively. Complex [Zn₂Ca(piv)₆(py)₂] was used as a source of secondary building units with binuclear and trinuclear cores to form porous frameworks. The structure and topology of the compounds have been analyzed in detail.

Keywords: heterometallic coordination polymers, porous polymers, secondary building unit, X-ray structure, topology.

Language: English

DOI: 10.1016/j.mencom.2020.11.011

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