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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2020 Volume 30, Issue 6, Pages 731–733 (Mi mendc1307)

This article is cited in 7 papers

Communications

Facile synthesis of temperature-sensitive ABA triblock copolymers by dispersion RAFT polymerization

N. S. Serkhachevaa, E. V. Chernikovab, M. S. Balashova, N. I. Prokopova, R. V. Tomsa

a M.V. Lomonosov Institute of Fine Chemical Technologies, MIREA - Russian Technological University, Moscow, Russian Federation
b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: The dispersion RAFT polymerization was applied for the first time to synthesize the well-defined ABA triblock copolymer core–shell nanoparticles of temperature-sensitive poly(N-isopropylacrylamide-co-acrylic acid)-block-poly(n-butyl acrylate)-block-poly(N-isopropylacrylamide-co-acrylic acid) and poly(n-butyl acrylate-co-N-isopropylacrylamide)-blockpoly(n-butyl acrylate)-block-poly(n-butyl acrylate-co-N-isopropylacrylamide).

Keywords: reversible addition–fragmentation chain transfer (RAFT), RAFT polymerization, dispersion polymerization, self-assembly, block copolymers, temperature-sensitive polymers.

Language: English

DOI: 10.1016/j.mencom.2020.11.014



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