I. I. Ponomarev, K. M. Skupov, K. A. Lyssenko, I. V. Blagodatskikh, A. V. Muranov, Yu. A. Volkova, D. Yu. Razorenov, I. I. Ponomarev, L. E. Starannikova, D. A. Bezgin, A. Yu. Alentiev, Yu. P. Yampolskii, “New PIM-1 copolymers containing 2,3,6,7-anthracenetetrayl moiety and their use as gas separation membranes”, Mendeleev Commun., 2020, Volume 30, Issue 6,Pages <nobr>734

This article is cited in 7 papers

Communications

New PIM-1 copolymers containing 2,3,6,7-anthracenetetrayl moiety and their use as gas separation membranes

I. I. Ponomarev^a, K. M. Skupov^a, K. A. Lyssenko^b, I. V. Blagodatskikh^a, A. V. Muranov^a, Yu. A. Volkova^a, D. Yu. Razorenov^a, I. I. Ponomarev^a, L. E. Starannikova^c, D. A. Bezgin^c, A. Yu. Alentiev^c, Yu. P. Yampolskii^c

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^c A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: New PIM-1 copolymers with 2,3,6,7-anthracenetetrayl moiety have been synthesized as fine powders from 2,3,6,7-tetrahydroxy-9,10-di(p-fluorophenyl)anthracene monomer in DMSO, with crystal structure of the monomer as well as its precursors and the product of its model side crosslinking reaction being determined using X-ray diffraction. The microporosity and surface characteristics of the copolymers powders have been measured. As-cast membrane from the copolymer with 5 mol% of the monomer synthesized revealed promising gas separation properties as compared with original PIM-1.

Keywords: gas separation membrane, ladder polymer, polymer synthesis, copolymer, micropores, PIM-1, sonochemistry, BET.

Language: English

DOI: 10.1016/j.mencom.2020.11.015

	*Supplementary materials:*
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