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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2020 Volume 30, Issue 6, Pages 781–784 (Mi mendc1324)

This article is cited in 4 papers

Communications

Heterocyclization of amino alcohols into saturated cyclic quaternary ammonium salts

D. B. Vinogradov, P. V. Bulatov, E. Yu. Petrov, V. A. Tartakovsky

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Cyclodehydration of available N-alkylethanolamines with aldehydes and simultaneous or subsequent quaternization afford functionalized quaternary ammonium salts of N-nitroimidazolidine, oxazolidine and annulated bismorpholine type. Further replacement of their anions with residues of explosive acids provides a series of energyintensive quaternary salts with a rich hydrogen content possessing satisfactory energy characteristics and sufficiently high thermal stability.

Keywords: ammonium quaternary salts, amino alcohols, nitrates, nitramines, aldehydes, heterocyclization.

Language: English

DOI: 10.1016/j.mencom.2020.11.031



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