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JOURNALS // Mendeleev Communications // Archive
Mendeleev Commun., 2020 Volume 30, Issue 6, Pages 788–790 (Mi mendc1326)
This article is cited in 1 paper

Communications

Chemoselective vinylation of aminophenols with acetylene catalyzed by sodium aminophenolates in aqueous DMSO

L. A. Oparina, N. A. Kolyvanov, N. K. Gusarova, B. A. Trofimov

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation

Abstract: An efficient atom-economic chemoselective synthesis of vinyloxyanilines from aminophenols and acetylene catalyzed by sodium aminophenolates in aqueous DMSO (90°C, 3h) has been developed.

Keywords: acetylene, aminophenols, superbases, nucleophilic addition, vinylation, vinyloxyanilines.

Language: English

DOI: 10.1016/j.mencom.2020.11.033


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