E. S. Sorin, R. K. Baimuratova, V. V. Tkachev, A. N. Utenyshev, A. V. Kuzmin, G. I. Dzhardimalieva, “Structure and properties of the metal-containing monomer based on nickel acrylate and 4'-phenyl-2,2':6',2''-terpyridine for self-healing polymers”, Mendeleev Commun., 2024, Volume 34, Issue 3,Pages <nobr>382

This article is cited in 3 papers

Communications

Structure and properties of the metal-containing monomer based on nickel acrylate and 4'-phenyl-2,2':6',2''-terpyridine for self-healing polymers

E. S. Sorin^a, R. K. Baimuratova^a, V. V. Tkachev^a, A. N. Utenyshev^a, A. V. Kuzmin^b, G. I. Dzhardimalieva^ac

^a Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
^b Yu.A. Osipyan Institute of Solid State Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
^c Moscow Aviation Institute (National Research University), Moscow, Russian Federation

Abstract: A new complex of nickel acrylate and 4’-phenyl-2,2’:6’,2’’- terpyridine, analogs of which have been previously used to obtain self-healing metallopolymers, has been prepared. The complex was analyzed by X-ray diffraction, IR and UV absorption spectroscopy, differential scanning calorimetry and thermogravimetric analysis. The values of effective activation energy of solid-phase polymerization and heat of double bond opening for this complex have been calculated.

Keywords: terpyridine, metal acrylates, nickel complexes, unsaturated complexes, crystal structure, self-healing.

Language: English

DOI: 10.1016/j.mencom.2024.04.022

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