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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2025 Volume 35, Issue 1, Pages 45–46 (Mi mendc1353)

This article is cited in 1 paper

Communications

Eight new trifluoromethyl derivatives of [60]fullerene, C60(CF3)16

N. B. Tamm, S. I. Troyanov

Department of Chemistry, M. V. Lomonosov Moscow State University, 119991 Moscow, Russian Federation

Abstract: Eight new C60(CF3)16 isomers have been synthesized by high-temperature trifluoromethylation of [60]fullerene with gaseous CF3I, isolated by HPLC, and structurally characterized by single crystal X-ray diffraction using synchrotron radiation.

Keywords: fullerene C60, trifluoromethylation, HPLC separation, structure elucidation, synchrotron radiation.

Received: 24.06.2024
Accepted: 16.08.2024

Language: English

DOI: 10.71267/mencom.7552



© Steklov Math. Inst. of RAS, 2025