A. V. Bochanov, S. A. Prikhod’ko, V. V. Bardin, N. Yu. Adonin, “Promising route to aryl(polyfluoroorganyl)borates: aryltris(pentafluorophenyl)borates”, Mendeleev Commun., 2025, Volume 35, Issue 2,Pages <nobr>128–129</nobr>

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Mendeleev Commun., 2025 Volume 35, Issue 2, Pages 128–129 (Mi mendc1361)

Communications

Promising route to aryl(polyfluoroorganyl)borates: aryltris(pentafluorophenyl)borates

A. V. Bochanov^ab, S. A. Prikhod’ko^a, V. V. Bardin^c, N. Yu. Adonin^a

^a G .K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation
^b Novosibirsk State University, 630090 Novosibirsk, Russian Federation
^c N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation

Abstract: Simple preparation of potassium aryltris(pentafluoro-phenyl)borates by nucleophilic perfluoroarylation of potassium aryltrifluoroborates with C₆F₅MgBr is offered.

Keywords: organofluoroborate anions, polyfluoroarylborates, nucleophilic perfluoroarylation, organofluorine compounds, organoboron compounds.

Received: 22.07.2024
Revised: 20.09.2024

Language: English

DOI: 10.71267/mencom.7575

	*Supplementary materials:*
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© Steklov Math. Inst. of RAS, 2025