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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2025 Volume 35, Issue 2, Pages 187–189 (Mi mendc1379)

Communications

Two-photonic photochemistry of NaBr in methanol solutions

I. A. Malakhovaab, V. P. Grivinb, E. M. Glebovb

a Technische Universität Dresden, 01069 Dresden, Germany
b V. V. Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation

Abstract: Two-photonic ionization of NaBr in methanol solutions at 266 nm was studied by nanosecond laser flash photolysis. The mechanism of photolysis includes reactions of a solvated electron and a dibromide radical anion. For quantitative description, two-photonic ionization of methanol should be taken into account.

Keywords: photochemistry, two-photonic processes, laser flash photolysis, methanol solutions, solvated electron, dibromide radical anion, sodium bromide.

Received: 02.09.2024
Accepted: 11.11.2024

Language: English

DOI: 10.71267/mencom.7607



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© Steklov Math. Inst. of RAS, 2025