N. B. Tamm, V. Yu. Markov, S. I. Troyanov, “Synthesis, HPLC isolation and structural characterization of three new C60(CF3)18 isomers”, Mendeleev Commun., 2025, Volume 35, Issue 2,Pages 130

Communications

Synthesis, HPLC isolation and structural characterization of three new C₆₀(CF₃)₁₈ isomers

N. B. Tamm, V. Yu. Markov, S. I. Troyanov

Department of Chemistry, M. V. Lomonosov Moscow State University, 119991 Moscow, Russian Federation

Abstract: Three new C₆₀(CF₃)₁₈ isomers have been synthesized by high-temperature trifluoromethylation of [60]fullerene with gaseous CF₃I, isolated by HPLC, and structurally characterized by single crystal X-ray diffraction using synchrotron radiation.

Keywords: fullerene C₆₀, trifluoromethylation, HPLC separation, synchrotron radiation, structure elucidation.

Received: 01.10.2024
Accepted: 12.11.2024

Language: English

DOI: 10.71267/mencom.7634