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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2025 Volume 35, Issue 3, Pages 324–326 (Mi mendc1397)

Communications

The feasible photoinduced growth of polycyclic aromatic hydrocarbons from cosmic benzene ice

V. A. Terashkevich, E. A. Pazyuk, A. V. Stolyarov

Department of Chemistry, M. V. Lomonosov Moscow State University, 119991 Moscow, Russian Federation

Abstract: The reactive phenyl radical, electronically excited benzene monomer and dimer, their radical cations and low-atomic neutral hydrocarbons may be born in situ via the photodissociation/photoionization of a gaseous benzene monomer/dimer photo-desorbed from cosmic ice as well as via the subsequent dissociative recombination of the arisen benzene cations. The above-mentioned species can be the sources for the assembly into large polycyclic aromatic hydrocarbons, which can occur at very low temperatures and pressures in the interstellar medium.

Keywords: astrochemistry, polycyclic aromatic hydrocarbons, benzene excimer, cosmic photochemistry, interstellar medium, ab initio calculation.

Received: 07.10.2024
Accepted: 15.11.2024

Language: English

DOI: 10.71267/mencom.7639



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© Steklov Math. Inst. of RAS, 2025