T. R. Akmalov, S. M. Masoud, D. V. Vorobyeva, F. M. Dolgushin, S. E. Nefedov, S. N. Osipov, “Monothiolate ruthenium alkylidene complexes with tricyclic fluorinated N-heterocyclic carbene ligands”, Mendeleev Commun., 2019, Volume 29, Issue 1,Pages <nobr>38

This article is cited in 4 papers

Communications

Monothiolate ruthenium alkylidene complexes with tricyclic fluorinated N-heterocyclic carbene ligands

T. R. Akmalov^a, S. M. Masoud^a, D. V. Vorobyeva^a, F. M. Dolgushin^a, S. E. Nefedov^b, S. N. Osipov^a

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: New monothiolate ruthenium alkylidene complexes bearing bulky tricyclic N-heterocyclic carbene ligands decorated with two geminal trifluoromethyl groups were synthesized. Their catalytic activity in representative olefin metathesis reactions, such as ring closing metathesis of diallyltosylamine and selfmetathesis of allylbenzene, has been evaluated.

Language: English

DOI: 10.1016/j.mencom.2019.01.011

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