N. A. Beliaev, T. V. Beryozkina, G. Lubec, V. A. Bakulev, “A catalyst-free one-step synthesis of <i>N</i>-pyrimidinyl amidines from endocyclic enamines and 4-azidopyrimidines”, Mendeleev Commun., 2019, Volume 29, Issue 1,Pages <nobr>50

This article is cited in 3 papers

Communications

A catalyst-free one-step synthesis of N-pyrimidinyl amidines from endocyclic enamines and 4-azidopyrimidines

N. A. Beliaev^a, T. V. Beryozkina^a, G. Lubec^b, V. A. Bakulev^a

^a Institute of Chemical Engineering, Ural Federal University, Ekaterinburg, Russian Federation
^b Paracelsus Medical University, Salzburg, Austria

Abstract: Novel N-pyrimidyl amidines of alycyclic acids were obtained in one step from of 4-azidopyrimidines and endocyclic enamines. The reaction mechanism involves [3 + 2]-addition of azide at the double bond followed by cleavage of thus formed 1,2,3-triazoline ring, and a contraction of alicycle.

Language: English

DOI: 10.1016/j.mencom.2019.01.015

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