V. A. Vil', E. S. Gorlov, O. V. Bityukov, I. B. Krylov, G. I. Nikishin, K. K. Pivnitsky, A. O. Terent'ev, “Oxidative C–O coupling as a new idea in the ‘click-like chemistry’: malonyl peroxides for the conjugation of two molecules”, Mendeleev Commun., 2019, Volume 29, Issue 2,Pages <nobr>132

This article is cited in 2 papers

Communications

Oxidative C–O coupling as a new idea in the ‘click-like chemistry’: malonyl peroxides for the conjugation of two molecules

V. A. Vil'^a, E. S. Gorlov^ab, O. V. Bityukov^a, I. B. Krylov^a, G. I. Nikishin^a, K. K. Pivnitsky^a, A. O. Terent'ev^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation

Abstract: Malonyl peroxides were used for the one-pot construction of hybrid structures by conjugation of heterocycle (3H-pyrazol-3-one, isoxazol-5(2H)-one, pyrazolidine-3,5-dione, or barbituric acid) and amine or alcohol. The first stage represents oxidative C–O coupling with liberation of the carboxyl group which is functionalized at the second stage thus affording ‘clicklike’ products with malonic linker.

Language: English

DOI: 10.1016/j.mencom.2019.03.003

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