V. D. Gvozdev, K. N. Shavrin, E. G. Baskir, O. M. Nefedov, M. P. Egorov, “Alkylthio(4-methylpent-3-en-1-ynyl)carbenes: generation by the photolysis of 5-alkylthioethynyl-3,3-dimethyl-3<i>H</i>-pyrazoles and reactions with alkenes”, Mendeleev Commun., 2019, Volume 29, Issue 2,Pages <nobr>140

This article is cited in 6 papers

Communications

Alkylthio(4-methylpent-3-en-1-ynyl)carbenes: generation by the photolysis of 5-alkylthioethynyl-3,3-dimethyl-3H-pyrazoles and reactions with alkenes

V. D. Gvozdev, K. N. Shavrin, E. G. Baskir, O. M. Nefedov, M. P. Egorov

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: New singlet alkylthio(4-methylpent-3-en-1-ynyl)carbenes were generated by photolysis of corresponding 5-alkylthioethynyl-3,3-dimethyl-3H-pyrazoles and subsequently trapped by alkenes giving rise to 1-alkynyl-1-(alkylthio)cyclopropanes in yields up to 60%.

Language: English

DOI: 10.1016/j.mencom.2019.03.006

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