Z. Radai, V. Hodula, N. Z. Kiss, J. Koti, G. T. Keglevich, “Phosphorylation of (1-aryl-1-hydroxymethyl)phosphonates”, Mendeleev Commun., 2019, Volume 29, Issue 2,Pages <nobr>153

This article is cited in 13 papers

Communications

Phosphorylation of (1-aryl-1-hydroxymethyl)phosphonates

Z. Radai^a, V. Hodula^a, N. Z. Kiss^a, J. Koti^b, G. T. Keglevich^a

^a Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary
^b Spectroscopic Research Division, Gedeon Richter Plc., Budapest, Hungary

Abstract: The reaction of dimethyl (1-aryl-1-hydroxymethyl)phosphonates with 1-chloro-3-phospholene 1-oxides, diphenylphosphinic chloride or diphenyl chloridophosphonate affords the corresponding (1-phosphoryloxymethyl)phosphonates. The products with two different >P(O)– moieties exhibit characteristic δ_P shifts and ³J_P,P couplings in the ³¹P NMR spectra.

Language: English

DOI: 10.1016/j.mencom.2019.03.011

	*Supplementary materials:*
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