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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2019 Volume 29, Issue 3, Pages 260–262 (Mi mendc1489)

This article is cited in 5 papers

Communications

NMR investigation of photoinduced chiral inversion in (R)/(S)-naproxen–(S)-tryptophan linked system

A. A. Ageeva, S. V. Babenko, N. E. Polyakov, T. V. Leshina

V.V. Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: The inversion of the chiral centers in (R)/(S)-naproxen–(S)-tryptophan linked system under UV irradiation has been detected by the 1H NMR spectroscopy as an example of the (R,S)-diastereomer transformation into (S,S) analogue in an achiral environment.

Language: English

DOI: 10.1016/j.mencom.2019.05.006



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