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Mendeleev Commun., 2024 Volume 34, Issue 3, Pages 424–426 (Mi mendc149)

Communications

Leaching of non-ferrous metals using a microemulsion in the system sodium dodecyl sulfate–butanol–caproic acid–kerosene–water

N. M. Murashova, E. K. Sharapova

D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation

Abstract: The possibility of using reverse microemulsion based on sodium dodecyl sulfate containing an extractant caproic acid for the selective recovery of non-ferrous metals and their separation from iron in the process of microemulsion leaching has been demonstrated. Using a model system with a mixture of oxides, the following recovery factors of metals are achieved in 5 h of leaching (%): Cu, 47.6; Mn, 12.8; Ni, 9.4; Co, 9.1; Fe, 4.3. When leaching from a sample of oxidized cobalt–copper concentrate, the recovery of metals is as follows (%): Cu, 60.0; Co, 51.3; Mn, 16.5; Fe, 10.0; Ni, 9.3.

Keywords: microemulsion, leaching of metals, non-ferrous metals, sodium dodecyl sulfate, extractant, caproic acid, nanostructured media.

Language: English

DOI: 10.1016/j.mencom.2024.04.036



© Steklov Math. Inst. of RAS, 2025