D. V. Tsyganov, A. V. Samet, P. V. Dorovatovskii, V. N. Khrustalev, V. V. Semenov, “Arylglyoxal oximes as putative C-nucleophiles in eliminative nucleophilic substitution process”, Mendeleev Commun., 2019, Volume 29, Issue 3,Pages <nobr>296

This article is cited in 3 papers

Communications

Arylglyoxal oximes as putative C-nucleophiles in eliminative nucleophilic substitution process

D. V. Tsyganov^a, A. V. Samet^a, P. V. Dorovatovskii^b, V. N. Khrustalev^bc, V. V. Semenov^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b National Research Centre 'Kurchatov Institute', Moscow, Russian Federation
^c Peoples Friendship University of Russia (RUDN University), Moscow, Russian Federation

Abstract: Reaction of arylglyoxal oximes ArCOCH=NOH (Ar=4-MeOC₆H₄, Ph) with 5-arylfurazanopyrazines proceeds as vicarious nucleophilic substitution of hydrogen in pyrazine ring with the elimination of hyponitrous acid, affording 5-(aroylmethylidene)-6-aryl-4H-furazano[3,4-b]pyrazines. Structure of the product was confirmed by X-ray diffraction.

Language: English

DOI: 10.1016/j.mencom.2019.05.018

	*Supplementary materials:*
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