B. I. Podlovchenko, Yu. M. Maksimov, D. O. Shkil, “Electrocatalytic properties of a Pd<sup>0</sup>(Pb) composite synthesized by galvanic displacement: activity towards formic acid oxidation”, Mendeleev Commun., 2019, Volume 29, Issue 3,Pages <nobr>312

This article is cited in 3 papers

Communications

Electrocatalytic properties of a Pd⁰(Pb) composite synthesized by galvanic displacement: activity towards formic acid oxidation

B. I. Podlovchenko, Yu. M. Maksimov, D. O. Shkil

Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: Galvanic displacement of electrodeposited lead by palladium fails to produce Pd shells. The anomalous ratio between formic acid electrooxidation reaction (FAOR) rates on Pd⁰(Pb) observed in HClO₄ and H₂SO₄ solutions is associated with the reduction of ClO₄⁻ anions to chloride ones which inhibit the FAOR.

Language: English

DOI: 10.1016/j.mencom.2019.05.024

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