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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2019 Volume 29, Issue 3, Pages 323–325 (Mi mendc1511)

This article is cited in 7 papers

Communications

Highly selective synthesis of tricyclic compounds from semithioglycoluril, formaldehyde and amines

V. V. Baranov, Ya. A. Barsegyan, N. G. Kolotyrkina, A. N. Kravchenko

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: A highly selective one-pot synthesis of new 6-substituted 4-thioxohexahydro-5H-2,3,4a,6,7a-pentaazacyclopenta[cd]inden-1(2H)-ones by cycloaminomethylation of semithioglycolurile with formaldehyde and amines is proposed. A mechanism for the process is suggested.

Language: English

DOI: 10.1016/j.mencom.2019.05.028



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