N. K. Gusarova, A. O. Sutyrina, V. A. Kuimov, S. F. Malysheva, N. A. Belogorlova, P. A. Volkov, B. A. Trofimov, “Single-stage synthesis of alkyl-<i>H</i>-phosphinic acids from elemental phosphorus and alkyl bromides”, Mendeleev Commun., 2019, Volume 29, Issue 3,Pages <nobr>328

This article is cited in 11 papers

Communications

Single-stage synthesis of alkyl-H-phosphinic acids from elemental phosphorus and alkyl bromides

N. K. Gusarova, A. O. Sutyrina, V. A. Kuimov, S. F. Malysheva, N. A. Belogorlova, P. A. Volkov, B. A. Trofimov

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation

Abstract: Elemental phosphorus (red or white) reacts with alkyl bromides at 60–62°C in the phase-transfer catalytic system KOH/H₂O/PhMe/Et₃BnNCl to afford alkyl-H-phosphinic acids in up to 47% yield.

Language: English

DOI: 10.1016/j.mencom.2019.05.030

	*Supplementary materials:*
		Supplementary_data_1.pdf	272.4 Kb