A. A. Shesterkina, L. M. Kozlova, I. V. Mishin, O. P. Tkachenko, G. I. Kapustin, V. P. Zakharov, M. S. Vlaskin, A. Z. Zhuk, O. A. Kirichenko, L. M. Kustov, “Novel Fe–Pd/γ-Al2O3 catalysts for the selective hydrogenation of C≡C bonds under mild conditions”, Mendeleev Commun., 2019, Volume 29, Issue 3,Pages 339

This article is cited in 13 papers

Communications

Novel Fe–Pd/γ-Al₂O₃ catalysts for the selective hydrogenation of C≡C bonds under mild conditions

A. A. Shesterkina^a, L. M. Kozlova^a, I. V. Mishin^a, O. P. Tkachenko^a, G. I. Kapustin^a, V. P. Zakharov^b, M. S. Vlaskin^b, A. Z. Zhuk^b, O. A. Kirichenko^a, L. M. Kustov^ac

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Joint Institute for High Temperatures, Russian Academy of Sciences, Moscow, Russian Federation
^c Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: Novel promising Fe–Pd/γ-Al₂O₃ catalysts for the selective liquid-phase hydrogenation of unsaturated compounds (phenylacetylene and 2-methylbut-3-yn-2-ol) under ambient conditions have been prepared. They were characterized by low temperature nitrogen adsorption, XRD, SEM, TEM, TPR-H₂ and DRIFTS-CO techniques. The presence of Pd–Fe nanoparticles led to increased reactivity and selectivity of the new catalysts in hydrogenation of the C≡C bond to the C=C one as compared to those of the Pd/Al₂O₃ system.

Language: English

DOI: 10.1016/j.mencom.2019.05.034

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