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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2019 Volume 29, Issue 4, Pages 380–381 (Mi mendc1529)

This article is cited in 8 papers

Communications

Simple H2-free hydrogenation of unsaturated monoterpenoids catalyzed by Raney nickel

A. A. Philippovab, A. M. Chibiryaevab, O. N. Martyanovab

a G.K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
b Novosibirsk State University, Novosibirsk, Russian Federation

Abstract: A series of monoterpenoids (citral, carvone, menthone, camphor) as well as cyclohexanone and hex-5-en-2-one were subjected to transfer hydrogenation with PriOH/Raney nickel system at 82 or 150°C. Among monoterpenoids, citral and carvone underwent full conversion at 82°C within 5h.

Language: English

DOI: 10.1016/j.mencom.2019.07.006



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