Ya. A. Pokusaeva, A. E. Koklin, V. V. Lunin, V. I. Bogdan, “CO<sub>2</sub> hydrogenation on Fe-based catalysts doped with potassium in gas phase and under supercritical conditions”, Mendeleev Commun., 2019, Volume 29, Issue 4,Pages <nobr>382

This article is cited in 17 papers

Communications

CO₂ hydrogenation on Fe-based catalysts doped with potassium in gas phase and under supercritical conditions

Ya. A. Pokusaeva^a, A. E. Koklin^a, V. V. Lunin^ab, V. I. Bogdan^ab

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: New catalysts FeK/Sibunit and FeCuK/Sibunit were prepared and applied for the CO₂ hydrogenation in the temperature range of 250–400°C and under the pressures of 1, 20 and 85atm. The reverse water gas shift reaction prevailed under the atmospheric pressure (i.e., CO₂ was selectively converted into CO), while the formation of C₁–C₁₂ hydrocarbons occurred under the increased pressures. The Cu-containing catalyst exhibited the higher activity and selectivity towards C₁–C₁₂ hydrocarbons.

Language: English

DOI: 10.1016/j.mencom.2019.07.007

	*Supplementary materials:*
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