V. Yu. Kotov, A. B. Ilyukhin, P. A. Buikin, Kh. E. Yorov, “Mixed halide hybrid halobismuthates and their <i>in situ</i> transformations”, Mendeleev Commun., 2019, Volume 29, Issue 5,Pages <nobr>537–540</nobr>

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Mendeleev Commun., 2019 Volume 29, Issue 5, Pages 537–540 (Mi mendc1583)

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Communications

Mixed halide hybrid halobismuthates and their in situ transformations

V. Yu. Kotov^ab, A. B. Ilyukhin^a, P. A. Buikin^ac, Kh. E. Yorov^ad

^a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b National Research University Higher School of Economics (HSE University), Moscow, Russian Federation
^c Higher Chemical College of the Russian Academy of Sciences, D.I. Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
^d Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: During a formation of four mixed hybrid halobismuthates (two of them have new structures) from solutions containing both Br⁻ and I⁻ ions, solid products enriched with iodine were isolated. Either oxidation or drying of mother liquors resulted in products with even higher iodine contents, up to pure iodobismuthates. All the compounds were characterized by a set of comprehensive methods (NMR, X-ray, DRS, etc.).

Language: English

DOI: 10.1016/j.mencom.2019.09.020

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