E. I. Knyazeva, A. I. Pylinina, I. I. Mikhalenko, “Relationship between the crystal structure, conductive and catalytic properties of perovskites Bi4Fe2xV2−2xO11−δ”, Mendeleev Commun., 2019, Volume 29, Issue 5,Pages 541

Communications

Relationship between the crystal structure, conductive and catalytic properties of perovskites Bi₄Fe_2xV_2−2xO_11−δ

E. I. Knyazeva, A. I. Pylinina, I. I. Mikhalenko

Peoples Friendship University of Russia (RUDN University), Moscow, Russian Federation

Abstract: The relationship between the crystal structure of bismuth vanadates Bi₄Fe_2xV_2−2xO_11−δ, where V⁵⁺ ions are partially replaced by Fe³⁺ cations, and their conductive properties and catalytic activities in conversions of isobutanol was established. A correlation between concentration of Fe ions, activation energy of dehydrogenation, and conductance activation energy was revealed.

Language: English

DOI: 10.1016/j.mencom.2019.09.021