M. A. Golubeva, A. L. Maksimov, “Catalytic system based on nickel(II) acetate and hypophosphorous acid for the selective hydrodeoxygenation of guaiacol”, Mendeleev Commun., 2019, Volume 29, Issue 5,Pages <nobr>550

This article is cited in 9 papers

Communications

Catalytic system based on nickel(II) acetate and hypophosphorous acid for the selective hydrodeoxygenation of guaiacol

M. A. Golubeva^a, A. L. Maksimov^ab

^a A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation
^b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: The title catalytic system exhibited high activity in the hydrogenation–hydrodeoxygenation of guaiacol (a low-molecular-weight product of lignin degradation). The conversion of guaiacol reached 97%, and the selectivity for cyclohexane was as high as 94%. Nickel phosphide phases were obtained in the reaction medium, and their presence determined the high activity of the catalytic system in the hydroconversion of guaiacol.

Language: English

DOI: 10.1016/j.mencom.2019.09.024

	*Supplementary materials:*
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