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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2019 Volume 29, Issue 5, Pages 573–574 (Mi mendc1595)

This article is cited in 1 paper

Communications

New bis-rhodium complex with a bidentate 3-phosphino-1,2,3,6-tetrahydrophosphinine P-ligand

I. L. Odinetsa, T. Körtvélyesib, R. Herbayc, P. Bagic, G. T. Keglevichc

a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
b Department of Physical Chemistry, University of Szeged, Szeged, Hungary
c Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary

Abstract: Reaction between the title bidental P-ligand (obtained from 4-chloro-5-methyl-1-phenyl-3-diphenylphosphoryl-l,2,3,6-tetrahydrophosphinine oxide by double deoxygenation using trichlorosilane or phenylsilane) and two equivalents of (Me5C5)RhCl2 led to the corresponding bis-RhIII complex whose structure was evaluated by ab initio and DFT calculations. Attempts to achieve selective complexation of either the ring or exocyclic P-function were unsuccessful.

Language: English

DOI: 10.1016/j.mencom.2019.09.032



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