O. S. Soficheva, G. E. Bekmukhamedov, A. B. Dobrynin, J. W. Heinicke, O. G. Sinyashin, D. G. Yakhvarov, “α-Diphenylphosphino-<i>N</i>-(pyrazin-2-yl)glycine as a ligand in Ni-catalyzed ethylene oligomerization”, Mendeleev Commun., 2019, Volume 29, Issue 5,Pages <nobr>575

This article is cited in 12 papers

Communications

α-Diphenylphosphino-N-(pyrazin-2-yl)glycine as a ligand in Ni-catalyzed ethylene oligomerization

O. S. Soficheva^a, G. E. Bekmukhamedov^ab, A. B. Dobrynin^a, J. W. Heinicke^c, O. G. Sinyashin^a, D. G. Yakhvarov^ab

^a A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation
^b A.M. Butlerov Chemistry Institute, Kazan Federal University, Kazan, Russian Federation
^c Institut fur Biochemie, Ernst-Moritz-Arndt Universitat Greifswald, Greifswald, Germany

Abstract: α-Diphenylphosphino-N-(pyrazin-2-yl)glycine was synthesized by the three-component condensation of diphenylphosphine, glyoxylic acid hydrate, and 2-aminopyrazine and its structure was confirmed by X-ray diffraction. It reacted with [Ni(COD)₂] (COD is cycloocta-1,5-diene) to give complexes that were tested as catalysts for selective dimerization/oligomerization of ethylene to but-1-ene (main product) and C₆–C₁₄ α-olefins, respectively.

Language: English

DOI: 10.1016/j.mencom.2019.09.033

	*Supplementary materials:*
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