I. E. Ushakov, A. S. Goloveshkin, E. N. Zorina-Tikhonova, A. S. Chistyakov, A. A. Sidorov, I. L. Eremenko, A. D. Volodin, A. V. Vologzhanina, “Synthesis, crystal structures and solid state reactions of zinc(ii) cyclobutane-1,1′-dicarboxylates containing 1,2-bis(pyrid-4 yl)ethylene”, Mendeleev Commun., 2019, Volume 29, Issue 6,Pages <nobr>643

This article is cited in 7 papers

Communications

Synthesis, crystal structures and solid state reactions of zinc(ii) cyclobutane-1,1′-dicarboxylates containing 1,2-bis(pyrid-4 yl)ethylene

I. E. Ushakov^a, A. S. Goloveshkin^a, E. N. Zorina-Tikhonova^b, A. S. Chistyakov^b, A. A. Sidorov^b, I. L. Eremenko^ab, A. D. Volodin^a, A. V. Vologzhanina^a

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Synthesis and response towards heating and UV irradiation of two novel zinc(II) cyclobutane-1,1′-dicarboxylate complexes were examined using X-ray diffraction, FT-IR and 1H NMR spectroscopy. One of the complexes underwent a photoinitiated solid state transformation of 1,2-bis(pyrid-4-yl)ethylene into 1,2,3,4-tetrakis(pyrid-4-yl)cyclobutane. A preliminary dehydration of this solid decreases the conversion rate of photoreaction.

Language: English

DOI: 10.1016/j.mencom.2019.11.012

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