A. G. Dedov, Ya. Z. Voloshin, A. S. Belov, A. S. Loktev, A. S. Bespalov, V. M. Buznik, “New heterogeneous catalytic systems based on highly porous ceramic materials modified with immobilized d-metal cage complexes for H2 production from CH4”, Mendeleev Commun., 2019, Volume 29, Issue 6,Pages 669

This article is cited in 5 papers

Communications

New heterogeneous catalytic systems based on highly porous ceramic materials modified with immobilized d-metal cage complexes for H₂ production from CH₄

A. G. Dedov^ab, Ya. Z. Voloshin^ab, A. S. Belov^b, A. S. Loktev^ab, A. S. Bespalov^c, V. M. Buznik^ac

^a National University of Oil and Gas ‘Gubkin University’, Moscow, Russian Federation
^b N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^c All-Russian Scientific Research Institute of Aviation Materials, Moscow, Russian Federation

Abstract: The Fe, Co and Ru clathrochelates bearing terminal polar groups were immobilized as the precursors of single atom catalysts on a surface of highly porous ceramic material used as the support. The obtained materials, which were evaluated for a syngas production from CH₄ based on its partial oxidation and dry reforming reactions, did not catalyze the partial oxidation of CH₄, while that based on immobilized Ru^II clathrochelate served as the active and selective catalyst of dry reforming conversion of CH₄+CO₂ mixture into a syngas containing the equimolar amounts of H₂ and CO.

Language: English

DOI: 10.1016/j.mencom.2019.11.022

	*Supplementary materials:*
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