E. Yu. Schmidt, I. A. Bidusenko, N. A. Cherimichkina, B. A. Trofimov, “Acetylene as driving and organizing molecule in the assembling reactions with chalcones in the NaOBu<sup>t</sup>/DMSO superbase system”, Mendeleev Commun., 2018, Volume 28, Issue 1,Pages <nobr>47

This article is cited in 4 papers

Communications

Acetylene as driving and organizing molecule in the assembling reactions with chalcones in the NaOBu^t/DMSO superbase system

E. Yu. Schmidt, I. A. Bidusenko, N. A. Cherimichkina, B. A. Trofimov

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation

Abstract: Acetylene reacts with chalcones in the NaOBu^t / DMSO superbase system (3–12 atm, 70°C, 15 min) to give, along with substituted furans, functionalized 3-exo-aryl-7-methylidene- 6,8-dioxabicyclo[3.2.1]octanes, novel frontalin congeners, which are diastereoselectively assembled from two molecules of chalcones and one molecule of acetylene.

Language: English

DOI: 10.1016/j.mencom.2018.01.015

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