B. A. Lozhkin, A. V. Shlyakhtin, V. V. Bagrov, P. V. Ivchenko, I. E. Nifant'ev, “Effective stereoselective approach to substituted 1,4-dioxane-2,5-diones as prospective substrates for ring-opening polymerization”, Mendeleev Commun., 2018, Volume 28, Issue 1,Pages <nobr>61

This article is cited in 21 papers

Communications

Effective stereoselective approach to substituted 1,4-dioxane-2,5-diones as prospective substrates for ring-opening polymerization

B. A. Lozhkin^a, A. V. Shlyakhtin^a, V. V. Bagrov^a, P. V. Ivchenko^ab, I. E. Nifant'ev^ab

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Intramolecular cyclization of α-bromoacyl derivatives of α-hydroxy acids affords 1,4-dioxane-2,5-diones. The method is suitable to obtain mono- and disubstituted products, the latter being formed stereoselectively as (S,S)-diastereomers, as confirmed by DFT modeling.

Language: English

DOI: 10.1016/j.mencom.2018.01.020

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