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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2018 Volume 28, Issue 1, Pages 76–78 (Mi mendc1669)

This article is cited in 19 papers

Communications

New sterically hindered bis-catechol, bis-o-quinone and its bis-triphenylantimony(v) bis-catecholate. 3,5-Di-tert-butyl-6-methoxymethylcatechol as alkylating agent

M. V. Arsenyev, T. V. Astaf'eva, E. V. Baranov, A. I. Poddel'sky, S. A. Chesnokov

G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod, Russian Federation

Abstract: Alkylation of 1,3,5-trimethoxybenzene with 3,5-di-tert-butyl-6-methoxymethylcatechol affords new sterically hindered biscatechol, whose oxidation gives the corresponding bis-o-quinone. Its treatment with triphenylstibine leads to bis-triphenylantimony(v) bis-catecholate.

Language: English

DOI: 10.1016/j.mencom.2018.01.025



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