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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2018 Volume 28, Issue 1, Pages 83–85 (Mi mendc1672)

This article is cited in 7 papers

Communications

Reaction of 2-methyl-3,4-dihydro-β-carbolin-2-ium iodide with acylmethyl halides controlled by electronic effects: a new route to 1,2-dihydroazepino[4,5-b]indoles

A. A. Zubenkoa, A. S. Morkovnikb, L. N. Divaevab, V. G. Kartsevc, G. S. Borodkinb, A. I. Klimenkod

a North-Caucasian Zonal Research Veterinary Institute, Novocherkassk, Russian Federation
b Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation
c 'InterBioScreen Ltd.', Chernogolovka, Moscow Region, Russian Federation
d Don State Agrarian University, Novocherkassk, Russian Federation

Abstract: 2-Methyl-3,4-dihydro-β-carbolin-2-ium iodide in the reaction with aryl halomethyl ketones is converted into 4- or/and 5-acyl-1,2-dihydroazepino[4,5-b]indoles depending on the electron donating effect of substituents in the aryl moiety of the halomethyl ketone.

Language: English

DOI: 10.1016/j.mencom.2018.01.028



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