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JOURNALS
// Mendeleev Communications
// Archive
Mendeleev Commun.,
2018
Volume 28,
Issue 2,
Pages
143–144
(Mi mendc1692)
This article is cited in
5
papers
Communications
Dioximes of 1,6-heptanediones from acetylene and ketones: only three atom-economic steps
E. Yu. Schmidt
ab
,
I. V. Tatarinova
a
,
N. I. Protsuk
a
,
I. A. Ushakov
a
,
B. A. Trofimov
a
a
A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation
b
Angarsk State Technical University, Angarsk, Russian Federation
Abstract:
2-Acetyl-3,4-dihydropyrans, synthesized from acetylene and ketones in two steps, react with hydroxylamine to afford 5-hydroxy-1,6-heptanedione dioximes (
E
,
E
-isomers) in 72–96% yields.
Language:
English
DOI:
10.1016/j.mencom.2018.03.010
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