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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2018 Volume 28, Issue 2, Pages 143–144 (Mi mendc1692)

This article is cited in 5 papers

Communications

Dioximes of 1,6-heptanediones from acetylene and ketones: only three atom-economic steps

E. Yu. Schmidtab, I. V. Tatarinovaa, N. I. Protsuka, I. A. Ushakova, B. A. Trofimova

a A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation
b Angarsk State Technical University, Angarsk, Russian Federation

Abstract: 2-Acetyl-3,4-dihydropyrans, synthesized from acetylene and ketones in two steps, react with hydroxylamine to afford 5-hydroxy-1,6-heptanedione dioximes (E,E-isomers) in 72–96% yields.

Language: English

DOI: 10.1016/j.mencom.2018.03.010



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