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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2018 Volume 28, Issue 2, Pages 145–146 (Mi mendc1693)

This article is cited in 6 papers

Communications

2,4,6-Trisubstituted 3,4-dihydropyrans from acetylene and ketones: deacetylation in the KOBut/DMSO system

E. Yu. Schmidtab, I. V. Tatarinovaa, I. A. Ushakova, B. A. Trofimova

a A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation
b Angarsk State Technical University, Angarsk, Russian Federation

Abstract: 2-Acetyl-3,4-dihydropyrans bearing 2-, 4- and 6-positioned aryl and alkyl groups, available from acetylene and ketones, undergo easy deacetylation in the KOBut/DMSO system (100 °C, 1.5 h) to give 2,4,6-trisubstituted dihydropyrans.

Language: English

DOI: 10.1016/j.mencom.2018.03.011



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