I. S. Mashkovsky, P. V. Markov, G. O. Bragina, G. N. Baeva, A. V. Rassolov, A. V. Bukhtiyarov, I. P. Prosvirin, V. I. Bukhtiyarov, A. Yu. Stakheev, “PdZn/α-Al2O3 catalyst for liquid-phase alkyne hydrogenation: effect of the solid-state alloy transformation into intermetallics”, Mendeleev Commun., 2018, Volume 28, Issue 2,Pages 152

This article is cited in 28 papers

Communications

PdZn/α-Al₂O₃ catalyst for liquid-phase alkyne hydrogenation: effect of the solid-state alloy transformation into intermetallics

I. S. Mashkovsky^a, P. V. Markov^a, G. O. Bragina^a, G. N. Baeva^a, A. V. Rassolov^a, A. V. Bukhtiyarov^b, I. P. Prosvirin^b, V. I. Bukhtiyarov^b, A. Yu. Stakheev^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b G.K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: The complex characterization of a PdZn /Al₂O₃ catalyst by XPS, XRD, TEM and H₂-TPD techniques revealed the route of solid-state alloy → intermetallics transformation. The influence of this transformation on the performance of PdZn /Al₂O₃ in the liquid-phase hydrogenation of diphenylacetylene was estimated.

Language: English

DOI: 10.1016/j.mencom.2018.03.014

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