I. N. Odin, M. V. Chukichev, M. V. Gapanovich, A. V. Vasiliev, G. F. Novikov, “Magnetic and luminescent properties of copper-deficient Cu1–x(In0.7Ga0.3)Se2 (0 < x ⩽ 0.32) solid solutions with chalcopyrite structure”, Mendeleev Commun., 2018, Volume 28, Issue 3,Pages 248

This article is cited in 6 papers

Communications

Magnetic and luminescent properties of copper-deficient Cu_1–x(In_0.7Ga_0.3)Se₂ (0 < x ⩽ 0.32) solid solutions with chalcopyrite structure

I. N. Odin^a, M. V. Chukichev^a, M. V. Gapanovich^b, A. V. Vasiliev^a, G. F. Novikov^ab

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation

Abstract: For synthesized copper-deficient Cu1 – x(In0.7Ga0.3)Se2 solid solutions with chalcopyrite structure, a monophase region within 0 < x ⩽ 0.32 interval was found for the first time and dependences of the unit cell parameters on x were determined. The magnetometry method revealed that the crystal lattice of Cu_{1 – x}(In_0.7Ga_0.3)Se₂ contains copper in both 2+ and 1+ oxidation states. The band with a maximum at 1.13eV in the cathode luminescence spectra of the above solid solutions with x of 0.1–0.3 is apparently due to Cu2+ VCu defect associates.

Language: English

DOI: 10.1016/j.mencom.2018.05.006