I. G. Tarkhanova, M. G. Gantman, A. S. Sigeev, K. I. Maslakov, V. M. Zelikman, I. P. Beletskaya, “Highly efficient Sandmeyer reaction on immobilized CuI/CuII-based catalysts”, Mendeleev Commun., 2018, Volume 28, Issue 3,Pages 261

This article is cited in 5 papers

Communications

Highly efficient Sandmeyer reaction on immobilized Cu^I/Cu^II-based catalysts

I. G. Tarkhanova^a, M. G. Gantman^b, A. S. Sigeev^c, K. I. Maslakov^a, V. M. Zelikman^a, I. P. Beletskaya^a

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b Friedrich-Alexander-Universität Erlangen-Nürnberg Lehrstuhl für Chemische Reaktionstechnik, Erlangen, Germany
^c A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Highly effective embodiment of Sandmeyer reaction has been revealed for Cu-based catalysts incorporating ionic liquid on Silochrom support. The most active catalyst (TOF = = 4000–8000 h^–1) contains comparable amounts of cuprous and cupric chloride anions. The reported method allows one to carry out the reaction for anilines in the one-pot mode.

Language: English

DOI: 10.1016/j.mencom.2018.05.010