O. L. Eliseev, T. N. Bondarenko, S. N. Britvin, P. P. Khodorchenko, A. L. Lapidus, “Efficient water-soluble catalytic system Rh<sup>I</sup>-CAP for biphasic hydroformylation of olefins”, Mendeleev Commun., 2018, Volume 28, Issue 3,Pages <nobr>264

This article is cited in 6 papers

Communications

Efficient water-soluble catalytic system Rh^I-CAP for biphasic hydroformylation of olefins

O. L. Eliseev^a, T. N. Bondarenko^a, S. N. Britvin^b, P. P. Khodorchenko^ac, A. L. Lapidus^ac

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Department of Geology, St. Petersburg State University, St. Petersburg, Russian Federation
^c National University of Oil and Gas ‘Gubkin University’, Moscow, Russian Federation

Abstract: Rhodium-catalysed hydroformylation of styrene and aliphatic olefins under biphasic conditions in the presence of watersoluble 1,4,7-triaza-9-phosphatricyclo[5.3.2.1^4,9]tridecane (CAP) chemoselectively affords aldehydes. Multiple catalyst reuse without loss in performance is demonstrated.

Language: English

DOI: 10.1016/j.mencom.2018.05.011