L. M. Kustov, A. L. Kustov, V. B. Kazanskii, “Spectroscopic investigation of redox and acidic properties of Co-substituted aluminophosphate CoAPO-11”, Mendeleev Commun., 2018, Volume 28, Issue 4,Pages <nobr>354

This article is cited in 5 papers

Communications

Spectroscopic investigation of redox and acidic properties of Co-substituted aluminophosphate CoAPO-11

L. M. Kustov^ab, A. L. Kustov^a, V. B. Kazanskii^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: Acid sites in Co-substituted aluminophosphate CoAPO-11 and its redox properties have been investigated using UV-VIS and IR spectroscopy. The acquired data revealed the absence of the bridged OH groups as a common feature of M^II-containing aluminophosphates. The behavior of Co²⁺/Co³⁺ couple in redox reactions was very different from that characteristic of supported cobalt ions.

Language: English

DOI: 10.1016/j.mencom.2018.07.003