M. E. Gurskii, G. D. Kolomnikova, S. V. Baranin, Yu. N. Bubnov, “Synthesis of 3,5-dimethyl-1-boraadamantane and its transformation into 3,5-dimethyl-1-azaadamantane”, Mendeleev Commun., 2018, Volume 28, Issue 4,Pages <nobr>366

This article is cited in 4 papers

Communications

Synthesis of 3,5-dimethyl-1-boraadamantane and its transformation into 3,5-dimethyl-1-azaadamantane

M. E. Gurskii^a, G. D. Kolomnikova^b, S. V. Baranin^a, Yu. N. Bubnov^ab

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The first synthesis of 3,5-dimethyl-1-boraadamantane from its easily available tetrahydrofuran adduct comprised sequential treatment with BuLi, AcCl, (Cy₂BH)₂ and heating. The compound was converted into its electronic ‘antagonist’, namely, 3,5-dimethyl-1-azaadamantane.

Language: English

DOI: 10.1016/j.mencom.2018.07.008

	*Supplementary materials:*
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