R. O. Iakovenko, A. D. Dilman, “Synthesis of halodifluoromethyl-substituted phosphines”, Mendeleev Commun., 2018, Volume 28, Issue 4,Pages <nobr>396

This article is cited in 3 papers

Communications

Synthesis of halodifluoromethyl-substituted phosphines

R. O. Iakovenko^a, A. D. Dilman^b

^a St. Petersburg National Research University of Information Technologies, Mechanics and Optics, St. Petersburg, Russian Federation
^b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Three phosphines bearing halodifluoromethyl group were obtained starting from chlorodiphenylphosphine. Silicon reagents Me₃SiCF₂X (X=Cl, Br) were used to install chloroor bromodifluoromethyl group to the phosphorus atom. Iododifluoromethyl-substituted phosphine was prepared by bromine/iodine exchange.

Language: English

DOI: 10.1016/j.mencom.2018.07.018