E. V. Motorina, T. N. Lomova, M. V. Klyuev, “Synthesis and properties of a novel porphyrin–fullerene triad assembled through donor–acceptor bonding”, Mendeleev Commun., 2018, Volume 28, Issue 4,Pages <nobr>426

This article is cited in 21 papers

Communications

Synthesis and properties of a novel porphyrin–fullerene triad assembled through donor–acceptor bonding

E. V. Motorina^a, T. N. Lomova^a, M. V. Klyuev^b

^a G.A. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo, Russian Federation
^b Department of Chemistry and Biology, Ivanovo State University, Ivanovo, Russian Federation

Abstract: Complexation of (hydroxy)(oxo)(5,10,15,20-tetraphenylporphyrinato) molybdenum(v) with 2’,5’-di(2-pyridyl)-1’-(3-pyridylmethyl) pyrrolidino[70]fullerene leading to a new donor–acceptor triad is characterized by quantitative description of the equilibrium and the reaction rate. The prospects of the triad as a photosynthetic antenna imitator and an active layer in solar energy conversion devices are substantiated.

Language: English

DOI: 10.1016/j.mencom.2018.07.029

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