I. E. Nifant'ev, A. A. Vinogradov, A. A. Vinogradov, A. V. Churakov, P. V. Ivchenko, “Synthesis of zirconium(III) complex by reduction of O[SiMe2(η5-C5H4)]2ZrCl2 and its selectivity in catalytic dimerization of hex-1-ene”, Mendeleev Commun., 2018, Volume 28, Issue 5,Pages 467

This article is cited in 9 papers

Communications

Synthesis of zirconium(III) complex by reduction of O[SiMe₂(η⁵-C₅H₄)]₂ZrCl₂ and its selectivity in catalytic dimerization of hex-1-ene

I. E. Nifant'ev^ab, A. A. Vinogradov^a, A. A. Vinogradov^a, A. V. Churakov^c, P. V. Ivchenko^ab

^a A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation
^b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^c N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: ansa-Complex O[SiMe₂(η⁵-C₅H₄)]₂ZrCl₂ upon reduction with LiAlH₄ in contrast to zirconocene dichloride forms a dia-magnetic Zr^III complex with the dimeric molecular structure proved by X-ray analysis. This complex after activation by MeAlO initiates oligomerization of α-olefins.

Language: English

DOI: 10.1016/j.mencom.2018.09.004

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