S. F. Malysheva, V. A. Kuimov, A. B. Trofimov, N. A. Belogorlova, Yu. I. Litvintsev, A. M. Belogolova, N. K. Gusarova, B. A. Trofimov, “2-Halopyridines in the triple reaction in the Pn/KOH/DMSO system to form tri(2-pyridyl)phosphine: Experimental and quantum-chemical dissimilarities”, Mendeleev Commun., 2018, Volume 28, Issue 5,Pages 472

This article is cited in 13 papers

Communications

2-Halopyridines in the triple reaction in the P_n/KOH/DMSO system to form tri(2-pyridyl)phosphine: Experimental and quantum-chemical dissimilarities

S. F. Malysheva, V. A. Kuimov, A. B. Trofimov, N. A. Belogorlova, Yu. I. Litvintsev, A. M. Belogolova, N. K. Gusarova, B. A. Trofimov

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation

Abstract: Experimental and quantum-chemical features of the triple nucleophilic substitution of halogen atoms in 2-chloro- and 2-bromopyridines under the action of P-centered nucleophiles generated in the system P_n/KOH/DMSO to afford tri(2-pyridyl)phosphine in a yield of up to 69% have been compared.

Language: English

DOI: 10.1016/j.mencom.2018.09.006

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