M. E. Minyaev, A. A. Vinogradov, A. V. Churakov, B. Kimmich, I. E. Nifant'ev, S. M. Nagy, P. V. Ivchenko, “Half-sandwich molybdenum complexes: molecular structure and catalyst precursors for olefin epoxidation with <i>tert</i>-butyl hydroperoxide”, Mendeleev Commun., 2018, Volume 28, Issue 5,Pages <nobr>508

This article is cited in 5 papers

Communications

Half-sandwich molybdenum complexes: molecular structure and catalyst precursors for olefin epoxidation with tert-butyl hydroperoxide

M. E. Minyaev^a, A. A. Vinogradov^a, A. V. Churakov^b, B. Kimmich^c, I. E. Nifant'ev^ad, S. M. Nagy^c, P. V. Ivchenko^d

^a A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation
^b N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^c Lyondell Chemical Co., Houston Technology Center, Channelview, TX, United States
^d Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: Half-sandwich carbonyl molybdenum complexes with bulky triphenylcyclopentadienyl and cyclopenta[b]thienyl ligands have been synthesized, analyzed by X-ray diffraction method and tested as precatalysts in α-olefin epoxidation with tert-butyl hydroperoxide.

Language: English

DOI: 10.1016/j.mencom.2018.09.019

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