E. Yu. Schmidt, I. A. Bidusenko, I. A. Ushakov, B. A. Trofimov, “Unfolding the frontalin chemistry: a facile selective hydrogenation of 7-methylidene-6,8-dioxabicyclo[3.2.1]octanes, 2:2 ensembles of ketones and acetylene”, Mendeleev Commun., 2018, Volume 28, Issue 5,Pages <nobr>513

This article is cited in 6 papers

Communications

Unfolding the frontalin chemistry: a facile selective hydrogenation of 7-methylidene-6,8-dioxabicyclo[3.2.1]octanes, 2:2 ensembles of ketones and acetylene

E. Yu. Schmidt^ab, I. A. Bidusenko^a, I. A. Ushakov^a, B. A. Trofimov^a

^a A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation
^b Angarsk State Technical University, Angarsk, Russian Federation

Abstract: Nickel-catalyzed low pressure hydrogenation of 1,5-diaryl-7-methylidene-6,8-dioxabicyclo[3.2.1]octanes proceeds chemo-specifically at the double bond and brings about mostly 1R*,3R*,5S*,7R* diastereomers.

Language: English

DOI: 10.1016/j.mencom.2018.09.021

	*Supplementary materials:*
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